FROM USGS website
The most significant climate impacts from volcanic injections into the stratosphere come from the conversion of sulfur dioxide to sulfuric acid, which condenses rapidly in the stratosphere to form fine sulfate aerosols. The aerosols increase the reflection of radiation from the Sun back into space, cooling the Earth's lower atmosphere or troposphere.
Several eruptions during the past century have caused a decline in the average temperature at the Earth's surface of up to half a degree (Fahrenheit scale) for periods of one to three years. The climactic eruption of Mount Pinatubo on June 15, 1991, was one of the largest eruptions of the twentieth century and injected a 20-million ton (metric scale) sulfur dioxide cloud into the stratosphere at an altitude of more than 20 miles. The Pinatubo cloud was the largest sulfur dioxide cloud ever observed in the stratosphere since the beginning of such observations by satellites in 1978. It caused what is believed to be the largest aerosol disturbance of the stratosphere in the twentieth century, though probably smaller than the disturbances from eruptions of Krakatau in 1883 and Tambora in 1815. Consequently, it was a standout in its climate impact and cooled the Earth's surface for three years following the eruption, by as much as 1.3 degrees F at the height of the impact.